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Gilbert MainesBuster Clarkson was once deliberately walked by Paige with the bases loaded.
Quincy Trouppe is another top quality ballplayer who was in MLB without a non-commemorative U.S. card being issued for him.
Fittingly, Willard Brown hit the first HR by a Black American in the Majors on 8/13/47.
There are others.
Among the others, Buck O'Neil was on the Cubs, but not as a player.