I would vote for pitchers Nolan Ryan, Steve Carlton and Bob Feller and definately Warren Spahn. All four were terrific pitchers, have nice signatures, and there signed balls can be had for $60 or less if you're patient.
Of the modern position players I like Tony Gwynn, Wade Boggs, Robin Yount, Pete Rose (even though he is one of the most prolific signers, I still love his autograph).
At $60 or less, there are lots to choose from, IMHO.
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