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Seth B.Mark, thanks for the correction, this is the sixth matchup. And it is indeed Pud Galvin and Tim Keefe who met on July 21st, 1892 before a crowd of 585. Keefe won 8-2.
By the way, Turner, I presume that's the Galvin OJ pic, gotta love them putting a man who pitched in over 700 games holding a bat!